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  1. Hiroki OSHIO | University of Tsukuba, Tsukuba | School of Science and.
  2. PDF (Gradient- and Spin-Echo) MRImaging: ANew Fast Clinical Imaging Technique'.
  3. Gradient- and spin-echo (GRASE) MR imaging: a long-existing technology.
  4. (PDF) Spin Canting in a Cobalt(II) Radical Complex with an Acentric.
  5. Spin crossover iron(III) complexes | Semantic Scholar.
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  7. Substituent dependence on the spin crossover behaviour of... - Europe PMC.
  8. Applications of Arterial Spin Labeled MRI in the Brain - PMC.
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  12. Method and apparatus for spin-echo-train MR imaging using prescribed.
  13. Effect of N4-Substituent Choice on Spin Crossover in Dinuclear Iron(II.

Hiroki OSHIO | University of Tsukuba, Tsukuba | School of Science and.

The development and optimization of spin-echo-based, single-slab, three-dimensional techniques for magnetic resonance imaging of the whole brain are described. T1-weighted and T2-weighted image sets with a volume resolution of 1 mm3 and fluid-attenuated inversion-recovery image sets with a volume resolution of 3 mm3 were obtained in acquisition times of less than 10 minutes per image set. Cryomagnetic studies reveal that 1 and 2 show gradual spin crossover behavior, while 3 remains in the high spin state between 1.8 and 300 K. Full text links. Read article for free, from open access legal sources, via... , Cameron JM, Newton GN, Oshio H. Angew Chem Int Ed Engl, 58(17):5658-5662, 20 Mar 2019 Cited by: 0 articles.

PDF (Gradient- and Spin-Echo) MRImaging: ANew Fast Clinical Imaging Technique'.

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Gradient- and spin-echo (GRASE) MR imaging: a long-existing technology.

Room-temperature switchable materials showing multiple responses toward external stimuli are highly desired. Herein, we report bidirectional spin-state switch and fluorescence modulation of an Fe(II) complex (1) based on a rhodamine B 2-pyridinecarbaldehyde hydrazone ligand in both the solid state and solution.The complex is predominantly stabilized in the low-spin (LS) state at room. The aim of this study was the evaluation of a fast Gradient Spin Echo Technique (GraSE) for cardiac T2-mapping, combining a robust estimation of T2 relaxation times with short acquisition times. The sequence was compared against two previously introduced T2-mapping techniques in a phantom and in vivo. Phantom experiments were performed at 1.5 ;T using a commercially available cylindrical gel. X− = PF6−, 3) have been prepared, and crystallographically characterised as their methanol solvates. The solvate structures contain complexes that are fully.

(PDF) Spin Canting in a Cobalt(II) Radical Complex with an Acentric.

Abstract. Turbo spin-echo imaging (TSE; also known as Rapid Acquisition with Relaxation Enhancement, Fast Spin Echo, and Fast Acquisition Interleaved Spin Echo) can also be described as radiofrequency (RF) refocused echo-planar imaging (EPI) [25]. After a single RF excitation multiple RF refocusing pulses are applied, thus refocusing multiple. M. Guenther, K. Oshio and D. A. Feinberg, "Single-Shot 3D Imaging Techniques Improve Arterial Spin Labeling Perfusion Measurements," Magnetic Resonance in Medicine, Vol. 54, No. 2, 2005, pp. 491-498. doi10.1002/mrm.20580... Free SCIRP Newsletters. Add your e-mail address to receive free newsletters from SCIRP.

Spin crossover iron(III) complexes | Semantic Scholar.

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Principles and properties of the GRASE sequence. The pulse sequence diagram of the GRASE sequence is schematically shown in Figure 1 (6,7).It consists of multiple refocusing radiofrequency (RF) pulses after the excitation RF pulse just like the fast spin-echo (FSE) technique (), but with series of gradient-echo readouts in a way similar to EPI inserted in the echo spacing interval between.

Substituent dependence on the spin crossover behaviour of... - Europe PMC.

Herein, the syntheses, solid-state molecular structures, and characterization of two types of one-dimensional FeIII coordination polymers showing thermally induced spin crossover are reported. The reaction of [Fe(acen)Cl] (acen2− = N,N′-ethylenebis(acetylacetonylideneaminate) with 3,3′-bpy or 4,4′-bpy (bpy = bipyridine) produced zigzag and linear one-dimensional chain complexes, [Fe. Seven new dinuclear iron(II) complexes of the general formula [FeII2(PMRT)2](BF4)4·solvent, where PMRT is a 4-substituted-3,5-bis{[(2-pyridylmethyl)-amino]methyl}-4H-1,2,4-triazole, have been prepared in order to investigate the substituent effect on the spin crossover event. Variable temperature magnetic susceptibility and 57Fe Mössbauer spectroscopy studies show that two of the complexes.

Applications of Arterial Spin Labeled MRI in the Brain - PMC.

Sign In Create Free Account. You are currently offline. Some features of the site may not work correctly. DOI: 10.1016/S0010-8545(99)00243-X; Corpus ID: 97532027. Assembly of imino nitroxides with Ag(I) and Cu(I) ions... H. Oshio, Tasuku Ito; Published 2000; Chemistry; Coordination Chemistry Reviews.

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Hiroki Oshio It is promising and challenging to manipulate the electronic structures and functions of materials utilizing both metal‐to‐metal charge transfer (MMCT) and spin‐crossover (SCO) to tune.

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Assessment of arterial arrival times derived from multiple inversion time pulsed arterial spin labeling MRI. Magn Reson Med. 2010; 63:641-647. Crossref Medline Google Scholar; 31. Guenther M, Oshio K, Feinberg DA. Single-shot 3D imaging techniques improve arterial spin labeling perfusion measurements. Magn Reson Med. 2005; 54:491-498. Spin crossover in iron(III) compounds results in significant shortening of the metal-ligand bonds and averages 0.10-0.13... SCO chemistry are referred to the excellent reviews in 2004 and 2007 by van Koningsbruggen and Oshio , respectively. While we have tried to include as many papers as possible published over the last 8 years we are.

Method and apparatus for spin-echo-train MR imaging using prescribed.

Ship This Item — Qualifies for Free Shipping Buy Online, Pick up in Store... J.A. Réal: Spin Crossover in 1D, 2D and 3D Polymeric Iron(II) Networks.- P.J. van Koningsbruggen, Y. Maeda, H.Oshio: Iron(III) Spin Crossover Compounds. Show More. Editorial Reviews. From the reviews: "…The researcher just beginning to work in the field of. When used, it is most often an alternative to echo-planar and fast spin echo imaging for perfusion imaging, high-resolution, and 3D applications.... Oshio K. GRASE (Gradient- and spin-echo) MR imaging: A new fast clinical imaging technique. Radiology 1991;181:597-602.... Please help keep this site free for everyone in the world!. Hiroki OSHIO | Cited by 7,974 | of University of Tsukuba, Tsukuba | Read 283 publications | Contact Hiroki OSHIO.

Effect of N4-Substituent Choice on Spin Crossover in Dinuclear Iron(II.

Spin crossover (SCO) includes magnetic switching coupled with a reversible structural transformation around coordination spheres. 1 - 5 A metal ion changes spin state between high spin (HS) and low spin (LS). This switch is induced by an external stimulus, such as temperature, photoirradiation, or pressure, that changes the ligand field around the metal ion. Syntheses of high-spin and cluster molecules - Hiroki oshio (university of tsukuba). syntheses of high-spin and cluster. Probing spin and charge on the nanoscale - Craig j. hawker, university of california-santa barbara, dmr 11210523. afm... hn= g μB Bo • For a free electron • 2.00232 • For organic radicals • 1.99-2.01 • For. COLUMBUS, Ohio (WCMH) - Ohio State Fair goers can get free rides on the midway Sunday. There is a catch! You don't have to donate any money, win a funnel-cake-eating contest or spin in circles.


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